Beyond Li-ion: electrode materials for sodium- and magnesium-ion batteries

被引:256
作者
Masse, Robert C. [1 ]
Uchaker, Evan [1 ]
Cao, Guozhong [1 ,2 ,3 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
[3] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116023, Peoples R China
基金
美国国家科学基金会;
关键词
PROMISING CATHODE MATERIAL; RECHARGEABLE MG BATTERIES; ELECTROCHEMICAL ENERGY-STORAGE; GEL POLYMER ELECTROLYTE; CHEVREL-PHASE CATHODE; PRUSSIAN BLUE ANALOG; VANADIUM-OXIDE; CURRENT COLLECTORS; POSITIVE-ELECTRODE; CRYSTAL-STRUCTURE;
D O I
10.1007/s40843-015-0084-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The need for economical and sustainable energy storage drives battery research today. While Li-ion batteries are the most mature technology, scalable electrochemical energy storage applications benefit from reductions in cost and improved safety. Sodium-and magnesium-ion batteries are two technologies that may prove to be viable alternatives. Both metals are cheaper and more abundant than Li, and have better safety characteristics, while divalent magnesium has the added bonus of passing twice as much charge per atom. On the other hand, both are still emerging fields of research with challenges to overcome. For example, electrodes incorporating Na+ are often pulverized under the repeated strain of shuttling the relatively large ion, while insertion and transport of Mg2+ is often kinetically slow, which stems from larger electrostatic forces. This review provides an overview of cathode and anode materials for sodium-ion batteries, and a comprehensive summary of research on cathodes for magnesium-ion batteries. In addition, several common experimental discrepancies in the literature are addressed, noting the additional constraints placed on magnesium electrochemistry. Lastly, promising strategies for future study are highlighted.
引用
收藏
页码:715 / 766
页数:52
相关论文
共 294 条
[1]   Investigation of yttrium and polyvalent ion intercalation into nanocrystalline vanadium oxide [J].
Amatucci, GG ;
Badway, F ;
Singhal, A ;
Beaudoin, B ;
Skandan, G ;
Bowmer, T ;
Plitza, I ;
Pereira, N ;
Chapman, T ;
Jaworski, R .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :A940-A950
[2]   Progress in nonaqueous magnesium electrochemistry [J].
Amir, N. ;
Vestfrid, Y. ;
Chusid, O. ;
Gofer, Y. ;
Aurbach, D. .
JOURNAL OF POWER SOURCES, 2007, 174 (02) :1234-1240
[3]  
[Anonymous], 2011, ECS Transactions
[4]  
[Anonymous], PHYS REV B
[5]  
[Anonymous], RENEWABLE ENERGY POL
[6]  
[Anonymous], 2013, INT EN OUTL 2013 PRO
[7]  
[Anonymous], ENERGY ENV SCI
[8]  
[Anonymous], TECHNOLOGY MARKET DR
[9]  
[Anonymous], WORLD EN OUTL 2014
[10]   Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].
Armstrong, AR ;
Bruce, PG .
NATURE, 1996, 381 (6582) :499-500