A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst

被引：52

作者：

Davoodnia, Abolghasem ^{[1
]}

Zare-Bidaki, Atefeh ^{[1
]}

Behmadi, Hossein ^{[1
]}

机构：

[1] Islamic Azad Univ, Mashhad Branch, Dept Chem, Mashhad, Iran

来源：

CHINESE JOURNAL OF CATALYSIS | 2012年 / 33卷 / 11期

关键词：

1,8-dioxodecahydroacridine; solvent-tree condition; tetrabutylammonium hexatungstate; ONE-POT SYNTHESIS; SUPPORTED POLYPHOSPHORIC ACID; HIV-1 PROTEASE INHIBITORS; 1,2,4,5-TETRASUBSTITUTED IMIDAZOLES; DIMERIC 4-ARYL-1,4-DIHYDROPYRIDINES; RECYCLABLE CATALYST; BIGINELLI REACTION; CARBONYL-COMPOUNDS; EFFICIENT METHOD; FACILE SYNTHESIS;

D O I：

10.1016/S1872-2067(11)60449-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Tetrabutylammonium hexatungstate, [TBA](2)[W6O19], has been used as an efficient, inexpensive, and recyclable green catalyst for the one-pot three-component synthesis of 1,8-dioxodecahydroacridines by the reaction of dimedone with aromatic or aliphatic aldehydes in the presence of a nitrogen source (ammonium acetate or aromatic amines) under neat conditions. There are several advantages to the current process over the standard procedures available in the literature, including shorter reaction times (7-14 min), higher yields, facile work-up. and minimal environmental impact. Furthermore, the catalyst can be conveniently recovered and reused.

引用

页码：1797 / 1801

页数：5

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