Determination of Perfluorooctanoic Acid and Perfluorooctane Sulfonate in Lake Victoria Gulf Water

被引:44
作者
Orata, Francis [1 ]
Quinete, Natalia
Werres, Friedrich
Wilken, Rolf-Dieter [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Geowissensch, D-55099 Mainz, Germany
关键词
Perfluorooctane sulfonate; Perfluorooctanoic acid; LC/MS/MS; Lake Victoria; PERFLUORINATED ACIDS; TOXICITY;
D O I
10.1007/s00128-008-9543-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study we present a report of investigation from the screening of perfluorooctanoic acid and perfluorooctane sulfonate in Lake Victoria Gulf and in its source rivers. The first determined levels of perfluorinated alkylated substances in Lake Victoria ecosystem are presented. Variability in the concentrations of perfluorooctanoic acid or perfluorooctane sulfonate in river waters (range perfluorooctanoic acid 400-96,400 and perfluorooctane sulfonate < 400-13,230 pg/L) was higher than for Lake waters (range perfluorooctanoic acid 400-11,650 and perfluorooctane sulfonate < 400-2,530 pg/L respectively) suggesting generalized point sources such as domestic and industrial waste. The lowest limit of quantification was 400 pg/L for both analytes and limit of detection were 75 and 40 pg/L for perfluorooctanoic acid and perfluorooctane sulfonate respectively. Typical values for precision obtained were 0.14-3.7%, with concentrations range from 400 pg/mL to 1 mu g/mL).
引用
收藏
页码:218 / 222
页数:5
相关论文
共 19 条
[1]   Perfluorooctanoic acid-induced developmental toxicity in the mouse is dependent on expression of peroxisome proliferator-activated receptor-alpha [J].
Abbott, Barbara D. ;
Wolf, Cynthia J. ;
Schmid, Judith E. ;
Das, Kaberi P. ;
Zehr, Robert D. ;
Helfant, Laurence ;
Nakayama, Shoji ;
Lindstrom, Andrew B. ;
Strynar, Mark J. ;
Lau, Christopher .
TOXICOLOGICAL SCIENCES, 2007, 98 (02) :571-581
[2]  
Berger U., 2004, ORGANOHALOGEN COMPD, V66, P4046
[3]   Mechanisms of extrahepatic tumor induction by peroxisome proliferators in male CD rats [J].
Biegel, LB ;
Hurtt, ME ;
Frame, SR ;
O'Connor, JC ;
Cook, JC .
TOXICOLOGICAL SCIENCES, 2001, 60 (01) :44-55
[4]   Detection of perfluorooctane surfactants in Great Lakes water [J].
Boulanger, B ;
Vargo, J ;
Schnoor, JL ;
Hornbuckle, KC .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (15) :4064-4070
[5]   Toxicity of ammonium perfluorooctanoate in male cynomolgus monkeys after oral dosing for 6 months [J].
Butenhoff, J ;
Costa, G ;
Elcombe, C ;
Farrar, D ;
Hansen, K ;
Iwai, H ;
Jung, R ;
Kennedy, G ;
Lieder, P ;
Olsen, G ;
Thomford, P .
TOXICOLOGICAL SCIENCES, 2002, 69 (01) :244-257
[6]   Global distribution of perfluorooctane sulfonate in wildlife [J].
Giesy, JP ;
Kannan, K .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (07) :1339-1342
[7]  
GONZALEZBARREIR.C, 2006, ANAL BIOANAL CHEM, V386, P7, DOI DOI 10.1007/S00216-006-0557-4
[8]   Compound-specific, quantitative characterization of organic: Fluorochemicals in biological matrices [J].
Hansen, KJ ;
Clemen, LA ;
Ellefson, ME ;
Johnson, HO .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (04) :766-770
[9]   Accumulation of perfluorooctane sulfonate in marine mammals [J].
Kannan, K ;
Koistinen, J ;
Beckmen, K ;
Evans, T ;
Gorzelany, JF ;
Hansen, KJ ;
Jones, PD ;
Helle, E ;
Nyman, M ;
Giesy, JP .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (08) :1593-1598
[10]  
Kissa E., 2001, FLUORINATED SURFACTA