Facile synthesis and coupling of 3,9-dibromo-6-aryl-5H-dibenzo[d,f][1,3]diazepine derivatives

被引：8

作者：

Tomar, Manisha ^{[1
]}

Lucas, Nigel T. ^{[2
,3
]}

Muellen, Klaus ^{[4
]}

Jacob, Josemon ^{[1
]}

机构：

[1] Indian Inst Technol Delhi, Ctr Polymer Sci & Engn, New Delhi, India

[2] Univ Otago, Dept Chem, Dunedin 9054, New Zealand

[3] Univ Otago, MacDiarmid Inst Adv Mat & Nanotechnol, Dunedin 9054, New Zealand

[4] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 44期

关键词：

Diazepine; Suzuki coupling; Optical properties; Benzaldehyde; POLYMER SOLAR-CELLS; COPOLYMERS SYNTHESIS; CONJUGATED POLYMERS; EMITTING COPOLYMERS; HIGH-EFFICIENCY; 2,7-CARBAZOLE; LUMINESCENT; TRANSPORT; DONOR;

D O I：

10.1016/j.tetlet.2013.08.107

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A route has been developed to prepare 3,9-dibromo-6-aryl-5H-dibenzo[d,f][1,3]diazepine derivatives which undergo facile Suzuki coupling to generate extended conjugated moieties bearing this unit. Single crystal X-ray studies on three of the coupled products provide valuable information on the conformation and bulk packing of these materials.(C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：5883 / 5885

页数：3

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