Preparation, adsorption properties, and catalytic activity of 3D porous metal-organic frameworks composed of cubic building blocks and alkali-metal ions

被引：535
作者：
Zou, RQ
Sakurai, H
Xu, Q [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka 5638577, Japan
[2] Kobe Univ, Grad Sch Sci & Technol, Nada Ku, Kobe, Hyogo 6578501, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 16期
关键词：
adsorption; alkali metals; heterogeneous catalysis; metal-organic frameworks; nickel;
D O I：
10.1002/anie.200503923
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unexpected catalytic activity for the oxidation of CO to CO2 is exhibited by one of two novel 3D porous metal-organic frameworks in which [Ni8L12]20- (H3L = 4,5-imidazoledicarboxylic acid) cubic building blocks (CBBs) are linked by LiI or NaI ions. The clathrating ability towards Li I ions of such CBBs is seen in the X-ray crystal structure, which simulates the potential guest-bonding sites in the building blocks of the MOFs (see picture). (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2542 / 2546
页数：5
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