Preparation of aryl and heteroaryl indium(III) reagents by the direct insertion of indium in the presence of LiCl

被引：88
作者：
Chen, Yi-Hung [1 ]
Knochel, Paid [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 40期
关键词：
biaryls; cross-coupling; homogeneous catalysis; indium; palladium;
D O I：
10.1002/anie.200802292
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sensitive functional groups, including ketone, aldehyde, and ester groups, may be present in aryl indium reagents prepared in good to excellent yields by the treatment of aryl and heteroaryl iodides with indium powder in the presence of LiCl (see example). These functionalized organoindium(III) reagents readily undergo Pd-catalyzed cross-coupling with functionalized aryl iodides, including those containing NH or OH groups. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：7648 / 7651
页数：4
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