New high-nitrogen materials based on nitroguanyl-tetrazines: Explosive properties, thermal decomposition and combustion studies

被引：55

作者：

Chavez, DE ^{[1
]}

Tappan, BC ^{[1
]}

Hiskey, MA ^{[1
]}

Son, SF ^{[1
]}

Harry, H ^{[1
]}

Montoya, D ^{[1
]}

Hagelberg, S ^{[1
]}

机构：

[1] Los Alamos Natl Lab, DX2 Mat Dynam Grp, Dynam Experimentat Div, Los Alamos, NM 87545 USA

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2005年 / 30卷 / 06期

关键词：

explosive sensitivity; thermal decomposition; nitroguanyl-tetrazines;

D O I：

10.1002/prep.200500033

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper describes the explosive sensitivity and performance properties of two novel high-nitrogen materials, 3,6-bis-nitro-guanyl-1,2,4,5-tetrazine (1, (NQ(2)Tz)) and its corresponding bis-triaminoguanidinium salt (2, (TAG)(2)(NQ)(2)Tz)). These materials exhibit very low pressure dependence in burning rate. Flash pyrolysis/FTIR spectroscopy was performed, and insight into this interesting burning behavior was obtained. Our studies indicate that 1 and 2 exhibit highly promising energetic materials properties.

引用

页码：412 / 417

页数：6

共 17 条

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