Oxidized cellulose-Survey of the most recent achievements

被引:151
作者
Coseri, Sergiu [1 ]
Biliuta, Gabriela [1 ]
Simionescu, Bogdan C. [1 ,2 ]
Stana-Kleinschek, Karin [3 ]
Ribitsch, Volker [4 ]
Harabagiu, Valeria [1 ]
机构
[1] Petru Poni Inst Macromol Chem, Iasi 700487, Romania
[2] Gh Asachi Tech Univ Iasi, Dept Nat & Synthet Polymers, Iasi 700050, Romania
[3] Univ Maribor, Inst Engn Mat & Design, Fac Mech Engn, Lab Characterizat & Proc Polymers, SI-2000 Maribor, Slovenia
[4] Karl Franzens Univ Graz, Inst Chem Rheol & Colloid Sci, A-8010 Graz, Austria
关键词
Cellulose oxidation; TEMPO; N-hydroxyphthalimide (NHPI); Phthalimide-N-oxyl (PINO); Sodium periodate; PRIMARY ALCOHOL GROUPS; TEMPO-MEDIATED OXIDATION; HYDROXYPHTHALIMIDE (NHPI)/LEAD TETRAACETATE; PERIODATE OXYCELLULOSE; REGENERATED CELLULOSE; CARBONYL GROUPS; FIBERS; STARCH; ACID; ELECTROOXIDATION;
D O I
10.1016/j.carbpol.2012.03.086
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The functionalization and particularly the oxidation of cellulose is an intriguing and challenging topic due to the presence of multiple reactive sites, which can undergo specific reactions. The variety of the oxidizing agents used to improve the selectivity and yields of these transformations is illustrated by the steadily growing of the number of publications and patents reported. This paper is focused on the most selective agents for cellulose oxidations, i.e., sodium periodate and stable or non persistent nitroxyl radicals, emphasizing on the most recent developments reported so far. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:207 / 215
页数:9
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