adherend;
bioadhesive;
bond strength;
chitosan;
wood;
WATER RESISTANCE;
MOLECULAR-WEIGHT;
STRENGTH;
FILMS;
CHITIN;
FIBER;
D O I:
10.1002/app.38097
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
The potential of chitosan (CS) as wood adhesive was investigated in this study. The measurement of the bond strength of different CS-based formulations was carried out using double-lap shear tests. The best formulation tested was an adhesive composed of 6% of CS, 1% of glycerol, and 5 mmol/L of trisodium citrate dehydrate. Best bond strength from this formulation was found to be equal to 6.0 MPa in dried conditions and 1.6 MPa in wet conditions (specimens immersed for 3 h at 30 degrees C in water). The failure in the double-lap joint tests mainly occurred in wood. Finally, the penetration of the rhodamine-labeled CS at 4% in the pinewood matrix was also studied using microtome and microscopy techniques to show interactions between CS-based adhesive and wood. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2013