Luminescent ionic liquid formed from a melted rhenium(v) cluster

被引：20

作者：

Yanagisawa, Junichi ^{[1
]}

Hiraoka, Tomoaki ^{[1
]}

Kobayashi, Fumiya ^{[1
]}

Saito, Daisuke ^{[2
]}

Yoshida, Masaki ^{[2
]}

Kato, Masako ^{[2
]}

Takeiri, Fumitaka ^{[3
,4
]}

Kobayashi, Genki ^{[3
,4
]}

Ohba, Masaaki ^{[5
]}

Lindoy, Leonard F. ^{[6
]}

Ohtani, Ryo ^{[5
]}

Hayami, Shinya ^{[1
]}

机构：

[1] Kumamoto Univ, Dept Chem, Grad Sch Sci & Technol, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan

[2] Hokkaido Univ, Fac Sci, Dept Chem, Kita Ku, North 10 West 8, Sapporo, Hokkaido 0600810, Japan

[3] Inst Mol Sci, Dept Mat Mol Sci, 38 Nishigonaka, Okazaki, Aichi 4448585, Japan

[4] SOKENDAI Grad Univ Adv Studies, 38 Nishigonaka, Okazaki, Aichi 4448585, Japan

[5] Kyushu Univ, Fac Sci, Dept Chem, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[6] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 57期

关键词：

COORDINATION POLYMER; COMPLEXES; GLASSES; TETRACYANIDONITRIDORHENIUM(V);

D O I：

10.1039/d0cc02937h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently, non-crystalline coordination materials have been shown to represent a versatile class of functional materials. However, such materials incorporating metal complex clusters have remained largely unexplored. Herein, we demonstrate that a luminescent tetranuclear Re(V)cluster melts at 489 K, with the cluster structure being maintained in the corresponding supercooled ionic liquid phase.

引用

页码：7957 / 7960

页数：4

共 43 条

[1] Metal complexes as photo- and radiosensitizers [J].