Nerve agent simulant detection by using chromogenic triaryl methane cation probes

被引：34
作者：
Gotor, Raul [1 ,2 ]
Royo, Santiago [1 ,4 ]
Costero, Ana M. [1 ,2 ]
Parra, Margarita [1 ,2 ]
Gil, Salvador [1 ,2 ]
Martinez-Manez, Ramon [1 ,3 ,4 ]
Sancenon, Felix [1 ,3 ,4 ]
机构：
[1] Univ Valencia, Univ Politecn Valencia, Unidad Mixta, Ctr Reconocimiento Mol & Desarrollo Tecnol IDM, E-46100 Valencia, Spain
[2] Univ Valencia, Fac Quim, Dept Quim Organ, E-46100 Valencia, Spain
[3] Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain
[4] CIBER BBN, Madrid, Spain
来源：
TETRAHEDRON | 2012年 / 68卷 / 41期
关键词：
Chemical warfare; Chemosensor; Chromogenic; Triaryl methane dye; PROTOLYTIC EQUILIBRIA; PYRIDINE ANALOGUES; MALACHITE GREEN; SENSORS; SURFACE; MIMICS;
D O I：
10.1016/j.tet.2012.07.091
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Two triaryl methane cations have been used as probes for calorimetric detection of nerve agent simulants. Buffered mixed aqueous solutions of 1 and 2 showed bathochromic shifts in the presence of DCNP (diethylcyanophosphonate) and DCP (diethylchlorophosphate). The colour modulation can be observed to the naked eye. Appropriate mechanisms for the recognition event are proposed. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8612 / 8616
页数：5
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