Synthesis of novel dicationic basic ionic liquids and its catalytic activities for biodiesel production

被引：49

作者：

Fan, Mingming ^{[1
]}

Yang, Jing ^{[1
]}

Jiang, Pingping ^{[1
]}

Zhang, Pingbo ^{[1
]}

Li, Sisi ^{[1
]}

机构：

[1] Jiangnan Univ, Minist Educ, Sch Chem & Mat Engn, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China

来源：

RSC ADVANCES | 2013年 / 3卷 / 03期

基金：

中国国家自然科学基金;

关键词：

SOYBEAN OIL; TRANSESTERIFICATION; ACID;

D O I：

10.1039/c2ra22233g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biodiesel produced by transesterification of vegetable oils or animal fats is a potential alternative fuel to diesel, given the limited resources of fossil fuel and its environmental concerns. Three novel dicationic basic ionic liquids (DBILs) have been prepared for synthesis of biodiesel from soybean oil. Among them, 1, 2-bis (3-methylimidazolium-1-yl) ethylene imidazolide performed best and the yield of biodiesel reached 99.6%, which was related to the basicity and miscibility properties of the IL.

引用

页码：752 / 756

页数：5

共 31 条

[1] Opium poppy (Papaver somniferum L.) oil for preparation of biodiesel: Optimization of conditions [J].

Aksoy, Lacine .

APPLIED ENERGY, 2011, 88 (12) :4713-4718

[2] Structure and properties of high stability geminal dicationic ionic liquids [J].

Anderson, JL ;

Ding, RF ;

Ellern, A ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (02) :593-604

[3] Progress in biodiesel processing [J].

Balat, Mustafa ;

Balat, Havva .

APPLIED ENERGY, 2010, 87 (06) :1815-1835

[4] Synthesis and properties of new (μ-oxo)bis[trichloroferrate(III)] dianion salts incorporated with dicationic moiety [J].

Chang, Jui-Cheng ;

Ho, Wen-Yueh ;

Sun, I-Wen ;

Chou, Yu-Kai ;

Hsieh, Hsin-Hsiu ;

Wu, Tzi-Yi ;

Liang, Shih-Shin .

POLYHEDRON, 2010, 29 (15) :2976-2984

[5]

Chen XW, 2008, CHINESE J CATAL, V29, P957

[6] Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts [J].

Cole, AC ;

Jensen, JL ;

Ntai, I ;

Tran, KLT ;

Weaver, KJ ;

Forbes, DC ;

Davis, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5962-5963

[7] Biodiesel from an alkaline transesterification reaction of soybean oil using ultrasonic mixing [J].

Colucci, JA ;

Borrero, EE ;

Alape, F .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2005, 82 (07) :525-530

[8] Green synthesis of biodiesel using ionic liquids [J].

Earle, Martyn J. ;

Plechkova, Natalia V. ;

Seddon, Kenneth R. .

PURE AND APPLIED CHEMISTRY, 2009, 81 (11) :2045-2057

[9] The Effect of Alkoxide Ionic Liquids on the Synthesis of Dimethyl Carbonate from CO2 and Methanol over ZrO2-MgO [J].

Eta, Valerie ;

Maki-Arvela, Paivi ;

Salminen, Eero ;

Salmi, Tapio ;

Murzin, Dmitry Yu. ;

Mikkola, Jyri-Pekka .

CATALYSIS LETTERS, 2011, 141 (09) :1254-1261

[10] Dicationic Ionic Liquids as Environmentally Benign Catalysts for Biodiesel Synthesis [J].

Fang, Dong ;

Yang, Jinming ;

Jiao, Changmei .

ACS CATALYSIS, 2011, 1 (01) :42-47

← 1 2 3 4 →