Curiosity and simplicity in the invention and discovery of new metal-mediated reactions for organic synthesis

被引：24

作者：

Motherwell, WB ^{[1
]}

机构：

[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H OAJ, England

来源：

PURE AND APPLIED CHEMISTRY | 2002年 / 74卷 / 01期

关键词：

D O I：

10.1351/pac200274010135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two organometallic themes of current interest are presented. The scope and generality of the reductive deoxygenation of carbonyl compounds to organozinc carbenoids using zinc in combination with a silicon electrophile is discussed. Alkoxycyclopropanation can be achieved using orthoformates as substrates. Preliminary observations on the development of a rhodium-catalyzed tandem hydrosilylation-intramolecular aldol Sequence are discussed.

引用

页码：135 / 142

页数：8

共 18 条

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