Lithium-Sulfur Batteries

被引:41
作者
Bonnick, Patrick [1 ]
Nagai, Erika [1 ]
Muldoon, John [1 ]
机构
[1] Toyota Res Inst North Amer, Ann Arbor, MI 48105 USA
关键词
METAL ANODE; ELECTROLYTE; MATRIX;
D O I
10.1149/2.0031801jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Despite immense effort to solve the problem of lithium polysulfide dissolution in Li-S batteries, only partially successful solutions have been found for liquid-based electrolytes. Further research efforts to showcase new sulfur, positive electrode technologies should ensure they demonstrate commercially applicable sulfur loadings of > 3 mg/cm(2), electrolyte to sulfur weight ratios < 3 and current densities > C/2. Alternatively, by using solid electrolytes lithium polysulfide dissolution is eliminated and research can be refocused on the cell-limiting factor of reversibly stripping and plating Li metal without dendrite growth. (C) The Author(s) 2017. Published by ECS.
引用
收藏
页码:A6005 / A6007
页数:3
相关论文
共 28 条
[1]   The Electrochemical Characteristics and Applicability of an Amorphous Sulfide-Based Solid Ion Conductor for the Next-Generation Solid-State Lithium Secondary Batteries [J].
Aihara, Yuichi ;
Ito, Seitaro ;
Omoda, Ryo ;
Yamada, Takanobu ;
Fujiki, Satoshi ;
Watanabe, Taku ;
Park, Youngsin ;
Doo, Seokgwang .
FRONTIERS IN ENERGY RESEARCH, 2016, 4 (MAY)
[2]  
Bonnick P., 2015, THESIS
[3]   Inorganic-organic layer by layer hybrid membranes for lithium-sulfur batteries [J].
Bucur, Claudiu B. ;
Jones, Michael ;
Kopylov, Mykhailo ;
Spear, John ;
Muldoon, John .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (04) :905-911
[4]   A soft, multilayered lithium-electrolyte interface [J].
Bucur, Claudiu B. ;
Lita, Adrian ;
Osada, Naoki ;
Muldoon, John .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (01) :112-116
[5]   In-Situ Detection of Lithium Plating Using High Precision Coulometry [J].
Burns, J. C. ;
Stevens, D. A. ;
Dahn, J. R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (06) :A959-A964
[6]   Anodes for Rechargeable Lithium-Sulfur Batteries [J].
Cao, Ruiguo ;
Xu, Wu ;
Lv, Dongping ;
Xiao, Jie ;
Zhang, Ji-Guang .
ADVANCED ENERGY MATERIALS, 2015, 5 (16)
[7]   Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte [J].
Cheng, Eric Jianfeng ;
Sharafi, Asma ;
Sakamoto, Jeff .
ELECTROCHIMICA ACTA, 2017, 223 :85-91
[8]   A Review of Solid Electrolyte Interphases on Lithium Metal Anode [J].
Cheng, Xin-Bing ;
Zhang, Rui ;
Zhao, Chen-Zi ;
Wei, Fei ;
Zhang, Ji-Guang ;
Zhang, Qiang .
ADVANCED SCIENCE, 2016, 3 (03)
[9]   Dendrite-Free Nanostructured Anode: Entrapment of Lithium in a 3D Fibrous Matrix for Ultra-Stable Lithium-Sulfur Batteries [J].
Cheng, Xin-Bing ;
Peng, Hong-Jie ;
Huang, Jia-Qi ;
Wei, Fei ;
Zhang, Qiang .
SMALL, 2014, 10 (21) :4257-4263
[10]   Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells [J].
Hagen, Markus ;
Hanselmann, Dominik ;
Ahlbrecht, Katharina ;
Maca, Rudi ;
Gerber, Daniel ;
Tuebke, Jens .
ADVANCED ENERGY MATERIALS, 2015, 5 (16)