Determination of pseudorotation rates in E⊗e Jahn-Teller systems -: art. no. 014303

被引：6

作者：

Hands, ID ^{[1
]}

Dunn, JL ^{[1
]}

Bates, CA ^{[1
]}

机构：

[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England

来源：

PHYSICAL REVIEW B | 2006年 / 73卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1103/PhysRevB.73.014303

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple method employing the time-evolution operator is used to investigate the dynamical nature of the Jahn-Teller effect in the E circle times e system. This method allows analytical expressions for the rate of pseudorotation between potential wells to be determined as a function of the vibronic coupling parameters. A comparison is made with experimental data in the literature.

引用

页数：9

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