A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework

被引：1429

作者：

Uribe-Romo, Fernando J. ^{[2
]}

Hunt, Joseph R. ^{[2
]}

Furukawa, Hiroyasu ^{[2
]}

Klock, Cornelius ^{[2
]}

O'Keeffe, Michael ^{[1
]}

Yaghi, Omar M. ^{[2
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Ctr Reticular Chem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 13期

关键词：

RETICULAR SYNTHESIS; NETWORKS; POLYMERS; DATABASE; DESIGN; NETS;

D O I：

10.1021/ja8096256

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new crystalline porous three-dimensional. covalent organic framework, termed COF-300, has been synthesized and structurally characterized. Tetrahedral tetra-(4-anilyl)-methane and linear terephthaldehyde building Mocks were condensed to form imine linkages in a material whose X-ray crystal structure shows five independent diamond frameworks. Despite the interpenetration, the structure has pores of 7.2 angstrom diameter. Thus, COF-300 shows thermal stability up to 490 degrees C and permanent porosity with a surface area of 1360 m(2) g(-1).

引用

页码：4570 / +

页数：3

共 22 条

[1] Interpenetrating metal-organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural database [J].

Blatov, VA ;

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

CRYSTENGCOMM, 2004, 6 :377-395

[2] Three-periodic nets and tilings: minimal nets [J].

Bonneau, C ;

Delgado-Friedrichs, O ;

O'Keeffe, M ;

Yaghi, OM .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 :517-520

[3] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials [J].

Budd, PM ;

Ghanem, BS ;

Makhseed, S ;

McKeown, NB ;

Msayib, KJ ;

Tattershall, CE .

CHEMICAL COMMUNICATIONS, 2004, (02) :230-231

[4]

Calucci L., 2002, Chem. Eur. J, V8, P1520

[5] Reticular synthesis of microporous and mesoporous 2D covalent organic frameworks [J].

Cote, Adrien P. ;

El-Kaderi, Hani M. ;

Furukawa, Hiroyasu ;

Hunt, Joseph R. ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (43) :12914-+

[6] Porous, crystalline, covalent organic frameworks [J].

Côté, AP ;

Benin, AI ;

Ockwig, NW ;

O'Keeffe, M ;

Matzger, AJ ;

Yaghi, OM .

SCIENCE, 2005, 310 (5751) :1166-1170

[7] Thermodynamics of Guest-induced Structural Transitions in Hybrid Organic-Inorganic Frameworks [J].

Coudert, Francois-Xavier ;

Jeffroy, Marie ;

Fuchs, Alain H. ;

Boutin, Anne ;

Mellot-Draznieks, Caroline .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14294-14302

[8] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[9] Tetrahedral n-type materials:: Efficient quenching of the excitation of p-type polymers in amorphous films [J].

Ganesan, P ;

Yang, XN ;

Loos, J ;

Savenije, TJ ;

Abellon, RD ;

Zuilhof, H ;

Sudhölter, EJR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (42) :14530-14531

[10] HOW SHOULD CHEMISTS THINK [J].

HOFFMANN, R .

SCIENTIFIC AMERICAN, 1993, 268 (02) :66-73

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