Di-μ-chlorido-bis{[2-(8-quinolyloxy)-acetato-κ3N,O1,O2]copper(II)}

被引:9
作者
Wang, Zhi-hong [1 ]
Fan, Jun [1 ]
Zhang, Wei-guang [1 ]
Wang, Jun [1 ]
机构
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
基金
中国国家自然科学基金;
关键词
D O I
10.1107/S1600536808031656
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu-2(C11H8NO3)(2)Cl-2], is a bicopper(II) complex. Each Cu-II ion is five-coordinated by two O atoms and one N atom from the (8-quinolyloxy) acetate ligand, and by two mu(2)-chloride ligands, thus exhibiting a distorted square-pyramidal CuCl2NO2 coordination environment. Each (8-quinolyloxy) acetate anion acts as a tridentate chelating ligand. In the crystal structure, adjacent quinolyl rings are involved in strong pi-pi stacking interactions, with interplanar distances of 3.549 (5) and 3.763 (5) angstrom, thereby forming a two-dimensional planar network perpendicular to the ab plane. Furthermore, a weak interaction [2.750 (4) angstrom] is observed within these planes between one Cu-II ion and a carboxylate O atom from a ligand in an adjacent molecule, which also contributes to the stability of the structure.
引用
收藏
页码:M1446 / U924
页数:12
相关论文
共 12 条
[1]  
[Anonymous], J AM CHEM SOC
[2]  
[Anonymous], 2004, APEX2
[3]   Temperature-dependent synthesis of metal-organic frameworks based on a flexible tetradentate ligand with bidirectional coordination donors [J].
Dong, Yu-Bin ;
Jiang, You-Yun ;
Li, Jie ;
Ma, Jian-Ping ;
Liu, Feng-Ling ;
Tang, Bo ;
Huang, Ru-Qi ;
Batten, Stuart R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (15) :4520-+
[4]  
Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565
[5]   Synthesis, structure, luminescence, and water induced reversible crystal-to-amorphous transformation properties of lanthanide(III) benzene-1,4-dioxylacetates with a three-dimensional framework [J].
Hong, Xian-Lan ;
Li, Yi-Zhi ;
Hu, Huaimin ;
Pan, Yi ;
Bai, Junfeng ;
You, Xiao-Zeng .
CRYSTAL GROWTH & DESIGN, 2006, 6 (06) :1221-1226
[6]  
SAINT, 1999, SAINT
[7]  
Sheldrick G. M., 1996, SADABS PROGRAM EXPIR
[8]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[9]   Design, synthesis, structure, and gas (N2, Ar, CO2, CH4, and H2) sorption properties of porous metal-organic tetrahedral and heterocuboidal polyhedra [J].
Sudik, AC ;
Millward, AR ;
Ockwig, NW ;
Côté, AP ;
Kim, J ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :7110-7118
[10]   A novel three-dimensional triangular organic-inorganic hybrid network self-assembled by mononuclear [Mn(4,4′-bipyridine)2(H2O)4]2+ cations and rich solvate 4,4′-bipyridine molecules through hydrogen-bonding and π-π interactions [J].
Tong, ML ;
Lee, HK ;
Chen, XM ;
Huang, RB ;
Mak, TCW .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (21) :3657-3659