Multi-Bond Forming Processes in Efficient Synthesis

被引:39
作者
Green, Nicholas J. [1 ]
Sherburn, Michael S. [1 ]
机构
[1] Australian Natl Univ, Res Sch Chem, Australian Res Council Ctr Excellence Free Rad Ch, Canberra, ACT 0200, Australia
基金
澳大利亚研究理事会;
关键词
ENANTIOSELECTIVE TOTAL-SYNTHESIS; RING-CLOSING METATHESIS; ENDIANDRIC ACID CASCADE; ONE-POT SYNTHESIS; COMBINING 2-DIRECTIONAL SYNTHESIS; STEREOCONTROLLED TOTAL-SYNTHESIS; CATALYZED POLYENE CYCLIZATIONS; BIOMIMETIC TOTAL-SYNTHESIS; EPOXIDE-OPENING CASCADES; FORMAL TOTAL-SYNTHESIS;
D O I
10.1071/CH13003
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An increasing number of synthetic organic chemists are embracing the philosophy of efficiency. Herein we highlight multi-bond forming processes, which form two or more new covalent bonds in a single synthetic operation. Such processes, which have the ability to rapidly increase structural complexity, are preeminent in contemporary synthetic organic chemistry. In this short review we classify, analyse, and contrast contemporary multi-bond forming processes, frame these cutting edge contributions within a historical context, and speculate on likely future developments in the area.
引用
收藏
页码:267 / 283
页数:17
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