Highly loaded SnO2/mesoporous carbon nanohybrid with well-improved lithium storage capability

被引:52
作者
Chen, Lian [1 ]
Wu, Ping [1 ]
Wang, Hui [1 ]
Ye, Ya [1 ]
Xu, Bin [2 ]
Cao, Gaoping [2 ]
Zhou, Yiming [1 ]
Lu, Tianhong [1 ]
Yang, Yusheng [2 ]
机构
[1] Nanjing Normal Univ, Jiangsu Key Lab New Power Batteries, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Nanjing 210023, Jiangsu, Peoples R China
[2] Res Inst Chem Defense, Beijing 100191, Peoples R China
关键词
Tin oxide; Mesoporous carbon; Nanohybrid; Anode; Li-ion batteries; MESOPOROUS CARBON; ANODE MATERIAL; HIGH-CAPACITY; SNO2; NANOCRYSTALS; HOLLOW SPHERES; NANO-CACO3; NANOWIRES; COMPOSITE; ELECTRODE;
D O I
10.1016/j.jpowsour.2013.08.059
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reports the synthesis of highly loaded SnO2/mesoporous carbon (MC) nanohybrid through a facile chemical solution process and subsequent annealing methodology, by using a novel three-dimensional (3D) MC as a buffering and conducting matrix. Owing to its unique structural characteristics, the MC-SnO2 nanohybrid anode exhibits markedly improved cycling stability and rate capability compared to pure SnO2 nanoparticles, facilitating its application in advanced Li-ion batteries (LIBs) with long cycle life and high power density. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:178 / 183
页数:6
相关论文
共 29 条
[1]   SnO2-Based Nanomaterials: Synthesis and Application in Lithium-Ion Batteries [J].
Chen, Jun Song ;
Lou, Xiong Wen .
SMALL, 2013, 9 (11) :1877-1893
[2]   SnO2 Nanoparticles with Controlled Carbon Nanocoating as High-Capacity Anode Materials for Lithium-Ion Batteries [J].
Chen, Jun Song ;
Cheah, Yan Ling ;
Chen, Yuan Ting ;
Jayaprakash, N. ;
Madhavi, Srinivasan ;
Yang, Yan Hui ;
Lou, Xiong Wen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (47) :20504-20508
[3]   FePO4 nanoparticles embedded in a large mesoporous carbon matrix as a high-capacity and high-rate cathode for lithium-ion batteries [J].
Chen, Lian ;
Wu, Ping ;
Xie, Kongwei ;
Li, Jianping ;
Xu, Bin ;
Cao, Gaoping ;
Chen, Yu ;
Tang, Yawen ;
Zhou, Yiming ;
Lu, Tianhong ;
Yang, Yusheng .
ELECTROCHIMICA ACTA, 2013, 92 :433-437
[4]   One dimensional Si/Sn - based nanowires and nanotubes for lithium-ion energy storage materials [J].
Choi, Nam-Soon ;
Yao, Yan ;
Cui, Yi ;
Cho, Jaephil .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) :9825-9840
[5]   Synthesis of micro-sized SnO2@carbon hollow spheres with enhanced lithium storage properties [J].
Ding, Shujiang ;
Zhang, Dongyang ;
Wu, Hao Bin ;
Zhang, Zhicheng ;
Lou, Xiong Wen .
NANOSCALE, 2012, 4 (12) :3651-3654
[6]   SBA-15 derived carbon-supported SnO2 nanowire arrays with improved lithium storage capabilities [J].
Ding, Shujiang ;
Wang, Zhiyu ;
Madhavi, Srinivasan ;
Lou, Xiong Wen .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (36) :13860-13864
[7]   SnO2 nanosheet hollow spheres with improved lithium storage capabilities [J].
Ding, Shujiang ;
Lou, Xiong Wen .
NANOSCALE, 2011, 3 (09) :3586-3588
[8]   Facile synthesis of SnO2 nanocrystals coated conducting polymer nanowires for enhanced lithium storage [J].
Du, Zhijia ;
Zhang, Shichao ;
Jiang, Tao ;
Wu, Xiaomeng ;
Zhang, Lan ;
Fang, Hua .
JOURNAL OF POWER SOURCES, 2012, 219 :199-203
[9]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[10]   Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries [J].
Fan, J ;
Wang, T ;
Yu, CZ ;
Tu, B ;
Jiang, ZY ;
Zhao, DY .
ADVANCED MATERIALS, 2004, 16 (16) :1432-+