VUV irradiation of carbon dioxide (CO2) and ammonia (NH3) complexes in argon matrix

被引：17
作者：
Bossa, J. B.
Duvernay, F. [1 ]
Theule, P.
Borget, F.
Chiavassa, T.
机构：
[1] Univ Aix Marseille 1, UMR 6633, F-13397 Marseille 20, France
来源：
CHEMICAL PHYSICS | 2008年 / 354卷 / 1-3期
关键词：
Matrix isolation; FTIR spectroscopy; Photochemistry; Carbamic acid; Molecular complexes;
D O I：
10.1016/j.chemphys.2008.10.026
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, we characterized by FTIR spectroscopy the 1:1 and 2:1 molecular complexes between NH3 and CO2 in argon matrix at low temperature. In addition we tentatively identified the 1:2 molecular complex. The structures of the complexes were established from B3LYP calculations. Moreover, we showed that the VUV irradiation of the 1:1 complex forms the NH2OH:CO complex. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：211 / 217
页数：7
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