Selective hydrogenation of benzene to cyclohexene over RuCoB/γ-Al2O3 without additive

被引：58

作者：

Fan, Guang-Yin ^{[1
]}

Jiang, Wei-Dong ^{[1
]}

Wang, Jin-Bo ^{[1
]}

Li, Rui-Xiang ^{[1
]}

Chen, Hua ^{[1
]}

Li, Xian-Jun ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Sichuan, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 10卷 / 01期

关键词：

Benzene; Cyclohexene; Hydrogenation; Ruthenium; Cobalt; gamma-Alumina;

D O I：

10.1016/j.catcom.2008.08.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalyst RuCoB/gamma-Al2O3 was prepared by the reduction impregnation method and characterized by ICP, TEM, XRD, XPS, and TPR. The catalyst showed a high selectivity to cyclohexene for the partial hydrogenation of benzene without any additive. The high selectivity possibly results from that cobalt and boron cause the formation of electron-deficient ruthenium species. Under the optimum conditions, the maximum yield of cyclohexene reached 28.8%. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：98 / 102

页数：5

共 22 条

[1] The role of the titania and silica supports in Ru-Fe catalysts to partial hydrogenation of benzene
da-Silva, JW
Cobo, AJG
[J]. APPLIED CATALYSIS A-GENERAL, 2003, 252 (01) : 9 - 16
[2] Hu SC, 1998, J CHIN INST CHEM ENG, V29, P387
[3] Liquid phase hydrogenation of benzene to cyclohexene on ruthenium catalysts supported on zinc oxide-based binary oxides
Hu, SC
Chen, YW
[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2001, 76 (09) : 954 - 958
[4] Effect of preparation on Ru-Zn ultrafine catalysts in partial hydrogenation of benzene
Hu, SC
Chen, YW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (14) : 3127 - 3132
[5] Chemical vapor deposition of ruthenium oxide thin films from Ru(tmhd)3 using direct liquid injection
Lee, DJ
Kang, SW
Rhee, SW
[J]. THIN SOLID FILMS, 2002, 413 (1-2) : 237 - 242
[6] Liu S.C., 2006, J NAT GAS CHEM, V15, P319
[7] A novel amorphous alloy Ru-La-B/ZrO2 catalyst with high activity and selectivity for benzene selective hydrogenation
Liu, Shouchang
Liu, Zhongyi
Wang, Zheng
Zhao, Shuhui
Wu, Yongmei
[J]. APPLIED CATALYSIS A-GENERAL, 2006, 313 (01) : 49 - 57
[8] The effect of boron on selective benzene hydrogenation to cyclohexene over ruthenium boride powders
Liu, Z
Dai, WL
Liu, B
Deng, JF
[J]. JOURNAL OF CATALYSIS, 1999, 187 (01) : 253 - 256
[9] Benzene-selective hydrogenation to cyclohexene over supported ruthenium boride catalysts prepared by a novel method
Liu, Z
Xie, SH
Liu, B
Deng, JF
[J]. NEW JOURNAL OF CHEMISTRY, 1999, 23 (11) : 1057 - 1058
[10] Effect of promoters on the structures and properties of the RuB/γ-Al2O3 catalyst
Luo, G
Yan, SR
Qiao, MH
Fan, KN
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 230 (1-2) : 69 - 77

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