Synthesis of novel nanocomposite Fe3O4/ZrO2/chitosan and its application for removal of nitrate and phosphate

被引:185
作者
Jiang, Hualin [1 ,2 ,3 ]
Chen, Pinghua [3 ]
Luo, Shenglian [1 ,2 ,3 ]
Tu, Xinman [1 ,2 ,3 ]
Cao, Qun [3 ]
Shu, Meng [3 ]
机构
[1] Key Lab Jiangxi Prov Ecol Diag Remediat & Pollut, Nanchang 330063, Peoples R China
[2] Adv Lab POPs Cycl Utilizat & Control, Nanchang 330063, Peoples R China
[3] Nanchang Hangkong Univ, Coll Environm & Chem Engn, Nanchang 330063, Peoples R China
基金
中国国家自然科学基金;
关键词
Nitrate; Phosphate; ZrO2; Chitosan; Adsorption; Composite; AQUEOUS-SOLUTIONS; ADSORPTION; CHITOSAN; SORPTION; TARTRAZINE; ANIONS; IONS; DYES;
D O I
10.1016/j.apsusc.2013.04.013
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel nanocomposite with a BET surface area of 212.9 m(2)/g was synthesized from chitosan and Fe3O4/ZrO2 using an inexpensive protocol at mild condition. The Fe3O4/ZrO2/chitosan composite has the ability to adsorb both nitrate and phosphate. The maximum adsorption amount of nitrate and phosphate is 89.3 mg/g and 26.5 mg P/g, respectively. The adsorption process fits well to the pseudo-first-order kinetic rate model, and the mechanism involves simultaneous adsorption and intra-particle diffusion. The experimental results suggest that the composite is a promising adsorbent for treating water that is contaminated with nutrients. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码:942 / 949
页数:8
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