Facile synthesis of high-quality ultralong poly(aniline-co-p-phenylenediamine) nanofibers

被引：13

作者：

Li, Yan ^{[1
]}

Li, Guicun ^{[1
]}

Peng, Hongrui ^{[1
]}

Qin, Yong ^{[2
]}

Chen, Kezheng ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Lab Funct & Biol Nanomat, Qingdao 266042, Peoples R China

[2] Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China

来源：

SYNTHETIC METALS | 2013年 / 164卷

基金：

中国国家自然科学基金;

关键词：

Polyaniline; Conducting polymer; Copolymer; Chemical oxidative polymerization; Nanofibers; CONDUCTING POLYMER; LEAD IONS; POLYANILINE; NANOSTRUCTURES; ANILINE; SENSORS; GROWTH; ROUTE; ACID;

D O I：

10.1016/j.synthmet.2012.12.024

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

High-quality ultralong poly(aniline-co-p-phenylenediamine) nanofibers have been synthesized successfully by one-step chemical copolymerization of aniline and p-phenylenediamine using ammonium peroxydisulfate as the oxidant in aqueous solution. The addition of p-phenylenediamine in conventional polymerization system plays an important role in changing the bulk morphologies of polyaniline from irregular particle agglomerates to nanofibers. This process is rapid, facile, and free of any template and surfactant. The influences of synthetic parameters, such as the molar ratios of aniline and p-phenylenediamine, the molar ratios of monomer and ammonium peroxydisulfate, and the concentrations of HCl, on the morphologies and molecular structures of the resulting products have been investigated for elucidating the formation mechanism of poly(aniline-co-p-phenylenediamine) nanofibers. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：42 / 46

页数：5

共 39 条

[31] Facile synthesis of high-quality ZnS, CdS, CdZnS, and CdZnS/ZnS core/shell quantum dots: characterization and diffusion mechanism [J].

Liu, Xinmei ;

Jiang, Yang ;

Fu, Fengming ;

Guo, Weimin ;

Huang, Wenyi ;

Li, Lijun .

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2013, 16 (06) :1723-1729

[32] A green and facile hydrothermal approach for the synthesis of high-quality semi-conducting Sb2S3 thin films [J].

Liu, Meng ;

Gong, Yongshuai ;

Li, Zhilin ;

Dou, Meiling ;

Wang, Feng .

APPLIED SURFACE SCIENCE, 2016, 387 :790-795

[33] Facile synthesis of CuSe nanoparticles and high-quality single-crystal two-dimensional hexagonal nanoplatelets with tunable near-infrared optical absorption [J].

Wu, Yimin ;

Korolkov, Ilia ;

Qiao, Xvsheng ;

Zhang, Xianghua ;

Wan, Jun ;

Fan, Xianping .

JOURNAL OF SOLID STATE CHEMISTRY, 2016, 238 :279-283

[34] Synthesis of high-quality Ni2P hollow sphere via a template-free surfactant-assisted solvothermal route [J].

Wang, Xinjun ;

Wan, Fuquan ;

Gao, Youjun ;

Liu, Juan ;

Jiang, Kai .

JOURNAL OF CRYSTAL GROWTH, 2008, 310 (10) :2569-2574

[35] A facile approach to the synthesis of Er3+-Yb3+-Mo6+ co-doped TiO2/Yb2Ti2O7 electrospun nanofibers and high thermal sensitivity [J].

Liu, Kuichao ;

Ma, Ke ;

Tao, Hualong ;

Cui, Yan ;

Tian, Xingjian ;

Liu, Shimin ;

He, Ming ;

Dong, Bin ;

Song, Bo ;

Zhang, Zhihua .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2021, 99 (03) :557-564

[36] Facile Synthesis and Optimization of High-Performance H2S Gas Sensors Based on Pt-Co3O4@ZnO Nanofibers With Dual-MOF Structure [J].

Song, Xiaoyan ;

Wang, Hao ;

Pan, Zhaoyang ;

Huang, Wanchun ;

Wang, Zhipeng ;

Xing, Jinfeng .

IEEE SENSORS JOURNAL, 2025, 25 (09) :16101-16108

[37] The beneficial effect of CO2 in the low temperature synthesis of high quality carbon nanofibers and thin multiwalled carbon nanotubes from CH4 over Ni catalysts [J].

Corthals, Steven ;

Van Noyen, Jasper ;

Geboers, Jan ;

Vosch, Tom ;

Liang, Duoduo ;

Ke, Xiaoxing ;

Hofkens, Johan ;

Van Tendeloo, Gustaaf ;

Jacobs, Pierre ;

Sels, Bert .

CARBON, 2012, 50 (02) :372-384

[38] A facile approach to the synthesis of Er3+–Yb3+–Mo6+ co-doped TiO2/Yb2Ti2O7 electrospun nanofibers and high thermal sensitivity [J].

Kuichao Liu ;

Ke Ma ;

Hualong Tao ;

Yan Cui ;

Xingjian Tian ;

Shimin Liu ;

Ming He ;

Bin Dong ;

Bo Song ;

Zhihua Zhang .

Journal of Sol-Gel Science and Technology, 2021, 99 :557-564

[39] Superparamagnetic Poly(aniline-co-m-phenylenediamine)@Fe3O4 Nanocomposite as an Efficient Heterogeneous Catalyst for the Synthesis of 1H-pyrazolo[1,2-a]pyridazine-5,8-diones & 1H-pyrazolo[1,2-b]phthalazine-5, 10-diones Derivatives [J].

Nezhad, Shefa Mirani ;

Pourmousavi, Seied Ali ;

Zare, Ehsan Nazarzadeh .

CURRENT ORGANIC SYNTHESIS, 2022, 19 (02) :246-266

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