Enhanced performance of hybrid solar cells using carboxylic acid-functionalized graphene oxide supported TiO2 nanorod composites

被引:18
|
作者
Liu, Jincheng [1 ,2 ]
Wang, Yingjie [1 ]
Sun, Darren Delai [1 ]
机构
[1] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
[2] Aix Marseille Univ, Ctr Interdisciplinaire Nanosci Marseille, UPR 3118, CNRS, Marseille, France
基金
新加坡国家研究基金会;
关键词
Functionalized graphene oxide; TiO2; Composites; Hybrid solar cells; Nanorod; POLYMER PHOTOVOLTAIC CELLS; CONJUGATED POLYMER; ORGANIC-SOLVENTS; REDUCTION;
D O I
10.1016/j.matlet.2012.12.092
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We have successfully developed the carboxylic acid-functionalized graphene oxide-TiO2 nanorod composites (GO-COOH-TiO2) by a facile ligand exchange process in tetrahydrofuran. TiO2 nanorods were uniformly anchored on the surface of carboxylic acid functionalized graphene oxide (GO-COOH) sheet. The insulated oleic acid ligands are completely cleaned from the surface of TiO2 nanorods. The GO-COOH-TiO2 composite can effectively quench the photoluminescence of poly (3-hexylthiophene) (P3HT) and used as a good acceptor materials in hybrid solar cells. The P3HT/GO-COOH-TiO2 hybrid solar cell shows significantly improved property than P3HT/oleic acid capped TiO2 solar cell. Our work paved a new way to get well assembled TiO2 nanorod without insulated organic ligands for the photovoltaic application. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:178 / 181
页数:4
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