A Formal Total Synthesis of Platencin

被引：60

作者：

Austin, Kerrie A. B. ^{[1
]}

Banwell, Martin G. ^{[1
]}

Willis, Anthony C. ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 0200, Australia

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 20期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1021/ol801647h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The readily available and enantiomerically pure trienes 12 undergo a thermally induced intramolecular Diels-Alder reaction to give the corresponding mixture of compounds 13 and 14. This mixture has been elaborated to an advanced intermediate associated with Nicolaou's recently reported total synthesis of the natural enantiomeric form of the antibiotic platencin (2).

引用

页码：4465 / 4468

页数：4

共 40 条

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