kinetic modelling;
gas phase oxidative dehydrogenation;
ethane;
propane;
D O I:
10.1016/j.cattod.2005.11.027
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
Gas phase thermal and oxidative dehydrogenation of ethane and propane are explored experimentally and mikrokinetically. Kinetic data for the elementary reactions postulated were adopted from the literature. The results show that oxygen plays a dominating role in the primary activation of the alkanes by producing an HO2 center dot and a hydrocarbon radical. The kinetic sequences developed predict satisfactorily conversion and products yields for ethane and propane oxidative dehydrogenation. (c) 2005 Elsevier B.V. All rights reserved.
机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy
Beretta, A
Forzatti, P
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机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy
Forzatti, P
Ranzi, E
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h-index: 0
机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy
机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy
Beretta, A
Forzatti, P
论文数: 0引用数: 0
h-index: 0
机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy
Forzatti, P
Ranzi, E
论文数: 0引用数: 0
h-index: 0
机构:
Politecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, ItalyPolitecn Milan, Dipartimento Chim Ind & Ingn Chim G Natta, I-20133 Milan, Italy