Photocatalytic properties of amine functionalized Bi2Sn2O7/rGO nanocomposites

被引:41
作者
Gnanamoorthy, G. [1 ]
Muthamizh, S. [1 ]
Sureshbabu, K. [1 ]
Munusamy, S. [1 ]
Padmanaban, A. [1 ]
Kaaviya, A. [1 ]
Nagarajan, R. [2 ]
Stephen, A. [3 ]
Narayanan, V. [1 ]
机构
[1] Univ Madras, Dept Inorgan Chem, Guindy Campus, Madras 600025, Tamil Nadu, India
[2] Univ Hyderabad, Sch Chem UGC NRC, Telungana 500046, India
[3] Univ Madras, Dept Nucl Phys, Guindy Campus, Madras 600025, Tamil Nadu, India
关键词
Bi2Sn2O7; AF-Bi2Sn2O7; AF-Bi2Sn2O7/rGO nanocomposites; Thermal decomposition method; In-situ method; Photocatalytic degradation; ZINC-OXIDE; HYDROTHERMAL SYNTHESIS; THIN-FILMS; ELECTRODE; NANOPARTICLES; BI2O3; DEGRADATION; NANOSHEET; BEHAVIOR; DESIGN;
D O I
10.1016/j.jpcs.2018.02.042
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The binary metal oxide nanomaterials are having applications in various fields like sensors, optics, electrocatalyst and photocatalyst so on. Bi2Sn2O7 with pyrochlore structure is having low band gap energy; hence it is utilized in battery storage and gas sensor applications. In the present work, we have made an attempt to synthesis amine-functionalized Bi2Sn2O7/rGO nanocomposites by a thermal decomposition method and in-situ method; the synthesized nanocomposites were confirmed by XRD, FT-IR and Raman analysis. The AF-Bi2Sn2O7/rGO nanocomposites morphology was confirmed by FE-SEM along with EDX spectroscopy, we obtained different flowers and nest-like morphology. The pure and composite material band gap energy is decreases from 2.6 eV to 1.6 eV. All three nanomaterials Bi2Sn2O7, AF-Bi2Sn2O7, AF-Bi2Sn2O7/rGO nanocomposites (AF-amine functionalized) were utilized for the photocatalytic degradation of methylene blue dye under visible light irradiation. AF-Bi2Sn2O7/rGO nanocomposite showed an excellent photocatalytic activity than pure Bi2Sn2O7 and AF-Bi2Sn2O7.
引用
收藏
页码:21 / 31
页数:11
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