Iodine Mediated Addition of Trialkylamines to Dimethyl Acetylenedi-carboxylate

被引：1

作者：

Wu, Quanping ^{[1
]}

Liu, Hui-Fang ^{[2
]}

Zhang, Yue ^{[1
]}

Shen, Shiyu ^{[2
]}

Xue, Song ^{[2
]}

机构：

[1] Tianjin Univ Technol, Sch Elect Engn, Tianjin 300384, Peoples R China

[2] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin Key Lab Organ Solar Cells & Photochem Con, Tianjin 300384, Peoples R China

来源：

LETTERS IN ORGANIC CHEMISTRY | 2013年 / 10卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Dimethyl acetylenedicarboxylate; molecular iodine; addition reaction; trialkylamines; MOLECULAR-IODINE;

D O I：

10.2174/15701786113109990027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Addition reaction of tertiary amines to dimethyl acetylenedicarboxylate mediated by molecular iodine is described. The trialkylamines afford dealkylative adducts in moderate to good yields. Amines containing an aryl group react sluggishly in low yields with a loss of alkyl group.

引用

页码：617 / 621

页数：5

共 16 条

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