Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds

被引：68

作者：

Jiang, Jiewen ^{[1
]}

Liu, Jiajun ^{[1
]}

Yang, Ling ^{[1
]}

Shao, Ying ^{[2
]}

Cheng, Jiang ^{[2
]}

Bao, Xiaoguang ^{[1
]}

Wan, Xiaobing ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

[2] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 79期

关键词：

H INSERTION REACTIONS; CATALYZED CYCLOPROPANATION; DIAZO-COMPOUNDS; ENANTIOSELECTIVE CYCLOPROPANATION; ALKENES; COMPLEXES; MECHANISM; KETONES; POLYMERIZATIONS; HYDROPEROXIDES;

D O I：

10.1039/c5cc05183e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through merging Cu-based carbenes in a radical process, a novel crossover reaction has been successfully established, leading to the facile and efficient syntheses of various gamma-peroxy esters and 1,4-dicarbonyl compounds. Considering that both Cu-based carbene complexes and radicals are extremely reactive, and therefore exist only in extraordinarily low concentrations, the high selectivity of this coupling reaction is unusual.

引用

页码：14728 / 14731

页数：4

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