Formation of Nanodimensional 3C-SiC Structures from Rice Husks

被引:21
作者
Gorzkowski, E. P. [1 ]
Qadri, S. B. [1 ]
Rath, B. B. [1 ]
Goswami, R. [1 ]
Caldwell, J. D. [1 ]
机构
[1] USN, Res Lab, Washington, DC 20375 USA
关键词
beta-SiC; nanorods; rice husk; nanotubes;
D O I
10.1007/s11664-012-2421-y
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We have demonstrated that large quantities of beta-SiC nanostructures can be obtained from rice husk agricultural waste by using controlled conditions in a thermogravimetric setup. This simple and inexpensive method of producing these structures on a large scale is critical for applications in nanoelectronics, nanosensors, and biotechnology. The temperature and atmosphere are two critical elements in forming either alpha-cristobalite (SiO2) or beta-SiC. Using different characterization methods (x-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy), we have shown that pyrolysis of rice husks in argon atmosphere at 1375A degrees C results in simultaneous formation of carbon nanotubes, beta-SiC nanowires/nanorods, and beta-SiC powder.
引用
收藏
页码:799 / 804
页数:6
相关论文
共 12 条
[1]   Binder burnout and evolution of the mechanical strength of dry-pressed ceramics containing poly(vinyl alcohol) [J].
Baklouti, S ;
Bouaziz, J ;
Chartier, T ;
Baumard, JF .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (08) :1087-1092
[2]  
Callerame J, 1973, U. S. Patent, Patent No. [3754079 A, 3754079]
[3]  
Cullity B.D., 1978, ELEMENTS XRAY DIFFRA, V2nd, P102
[4]   SEPARATION OF PARTICLE SIZE AND LATTICE STRAIN IN INTEGRAL BREADTH MEASUREMENTS [J].
HALDER, NC ;
WAGNER, CNJ .
ACTA CRYSTALLOGRAPHICA, 1966, 20 :312-&
[5]   Ferrocenylethynylbenzenes as precursors to in situ synthesis of carbon nanotube and Fe nanoparticle compositions [J].
Keller, TM ;
Qadri, SB .
CHEMISTRY OF MATERIALS, 2004, 16 (06) :1091-1097
[6]   Effect of acid treatment on the formation of SiC whiskers from raw rice husks [J].
Krishnarao, RV ;
Mahajan, YR .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1995, 15 (12) :1229-1234
[7]  
LEE JG, 1975, AM CERAM SOC BULL, V54, P195
[8]   Raman characterization of aligned carbon nanotubes produced by thermal decomposition of hydrocarbon vapor [J].
Li, WZ ;
Zhang, H ;
Wang, CY ;
Zhang, Y ;
Xu, LW ;
Zhu, K ;
Xie, SS .
APPLIED PHYSICS LETTERS, 1997, 70 (20) :2684-2686
[9]  
Nakashima S, 1997, PHYS STATUS SOLIDI A, V162, P39, DOI 10.1002/1521-396X(199707)162:1<39::AID-PSSA39>3.0.CO
[10]  
2-L