Field-induced periodic chiral pattern in the Nx phase of achiral bimesogens

被引:82
作者
Panov, V. P. [1 ]
Balachandran, R. [1 ]
Vij, J. K. [1 ]
Tamba, M. G. [2 ]
Kohlmeier, A. [2 ]
Mehl, G. H. [2 ]
机构
[1] Univ Dublin, Trinity Coll, Dept Elect & Elect Engn, Dublin 2, Ireland
[2] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England
基金
爱尔兰科学基金会;
关键词
NEMATIC LIQUID-CRYSTALS; DIMERS;
D O I
10.1063/1.4769458
中图分类号
O59 [应用物理学];
学科分类号
摘要
Some hydrocarbon-linked mesogenic dimers are known to exhibit an additional nematic phase (N-x) in the temperature range below the conventional nematic (N-u) phase. One of the features of this phase is the presence of optical response typically found in chiral systems, while the involved molecules are non-chiral. We demonstrate that the two domains of opposite handedness found in planar cells can be controlled/induced by the external electric field and these form periodic striped patterns. The effect of frequency and amplitude of the electric field on the periodicity and formation of the domain pattern is investigated. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4769458]
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页数:4
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共 15 条
[1]   AN ENHANCED ODD EVEN EFFECT OF LIQUID-CRYSTAL DIMERS ORIENTATIONAL ORDER IN THE ALPHA,OMEGA-BIS(4'-CYANOBIPHENYL-4-YL)ALKANES [J].
BARNES, PJ ;
DOUGLASS, AG ;
HEEKS, SK ;
LUCKHURST, GR .
LIQUID CRYSTALS, 1993, 13 (04) :603-613
[2]   Macroscopic Torsional Strain and Induced Molecular Conformational Deracemization [J].
Basu, Rajratan ;
Pendery, Joel S. ;
Petschek, Rolfe G. ;
Lemieux, Robert P. ;
Rosenblatt, Charles .
PHYSICAL REVIEW LETTERS, 2011, 107 (23)
[3]   The Chirality of a Twist-Bend Nematic Phase Identified by NMR Spectroscopy [J].
Beguin, Laetitia ;
Emsley, James W. ;
Lelli, Moreno ;
Lesage, Anne ;
Luckhurst, Geoffrey R. ;
Timimi, Bakir A. ;
Zimmermann, Herbert .
JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (27) :7940-7951
[4]   Phase behavior and properties of the liquid-crystal dimer 1",7"-bis(4-cyanobiphenyl-4′- yl) heptane: A twist-bend nematic liquid crystal [J].
Cestari, M. ;
Diez-Berart, S. ;
Dunmur, D. A. ;
Ferrarini, A. ;
de la Fuente, M. R. ;
Jackson, D. J. B. ;
Lopez, D. O. ;
Luckhurst, G. R. ;
Perez-Jubindo, M. A. ;
Richardson, R. M. ;
Salud, J. ;
Timimi, B. A. ;
Zimmermann, H. .
PHYSICAL REVIEW E, 2011, 84 (03)
[5]   Crucial role of molecular curvature for the bend elastic and flexoelectric properties of liquid crystals: mesogenic dimers as a case study [J].
Cestari, Mirko ;
Frezza, Elisa ;
Ferrarini, Alberta ;
Luckhurst, Geoffrey R. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (33) :12303-12308
[6]   Investigations on the flexoelectric and electroclinic effect in a cholesteric phase with twist inversion [J].
Dierking, I ;
Rudquist, P ;
Komitov, L ;
Lagerwall, ST ;
Stebler, B .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 304 :389-402
[7]   On the spontaneous symmetry breaking in the mesophases of achiral banana-shaped molecules [J].
Dozov, I .
EUROPHYSICS LETTERS, 2001, 56 (02) :247-253
[8]   Enantioselective segregation in achiral nematic liquid crystals [J].
Görtz, V ;
Goodby, JW .
CHEMICAL COMMUNICATIONS, 2005, (26) :3262-3264
[9]   Flexoelectricity and pattern formation in nematic liquid crystals [J].
Krekhov, Alexei ;
Pesch, Werner ;
Buka, Agnes .
PHYSICAL REVIEW E, 2011, 83 (05)
[10]   Converse Flexoelectric Effect in Bent-Core Nematic Liquid Crystals [J].
Kumar, Pramoda ;
Marinov, Y. G. ;
Hinov, H. P. ;
Hiremath, Uma S. ;
Yelamaggad, C. V. ;
Krishnamurthy, K. S. ;
Petrov, A. G. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (27) :9168-9174