The chemistry of Group 8 metal complexes with phosphinous acids and related P-OH ligands

被引：30

作者：

Francos, Javier ^{[1
]}

Elorriaga, David ^{[1
]}

Crochet, Pascale ^{[1
]}

Cadierno, Victorio ^{[1
]}

机构：

[1] Univ Oviedo, Ctr Innovac Quim Avanzada ORFEO CINQA, Lab Compuestos Organomet & Catalisis,IUQOEM, Dept Quim Organ & Inorgan,Fac Quim,Unidad Asociad, Julian Claveria 8, E-33006 Oviedo, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2019年 / 387卷

关键词：

P-OH ligands; Phosphinous acid ligands; Iron complexes; Ruthenium complexes; Osmium complexes; Homogeneous catalysis; H BOND ACTIVATION; CATALYZED C-H; ASYMMETRIC TRANSFER HYDROGENATION; DENSITY-FUNCTIONAL THEORY; X-RAY-DIFFRACTION; NITRILE HYDRATION; WHITE PHOSPHORUS; COORDINATION CHEMISTRY; RUTHENIUM COMPLEXES; DIRECT ARYLATIONS;

D O I：

10.1016/j.ccr.2019.02.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Despite their inherent instability, phosphinous acids PR2OH have emerged in recent years as a useful class of P-donor ligands for homogeneous catalysis. The present review article reports on the chemistry of Group 8 metal complexes containing such ligands and related P-OH species. Synthetic methodologies, reactivity studies, as well as the involvement of these compounds in a series of catalytic transformations, are presented. Remarkably, the non-innocent role played by the PR2OH ligands in the catalytic hydration of nitriles and C-H bond arylation processes has been revealed, evidencing their cooperation with the metal (ruthenium in most of the cases) in the activation of the substrates. (C) 2019 Elsevier B.V. All rights reserved.

引用

页码：199 / 234

页数：36

共 147 条

[1] Advances in Homogeneous Catalysis Using Secondary Phosphine Oxides (SPOs): Pre-ligands for Metal Complexes [J].