Direct phenol synthesis by selective oxidation of benzene with molecular oxygen on an interstitial-N/Re cluster/zeolite catalyst

被引：129

作者：

Bal, R

Tada, M

Sasaki, T

Iwasawa, Y ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Univ Tokyo, Dept Complex Sci & Engn, Grad Sch Frontier Sci, Kashiwa, Chiba 2778561, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期

关键词：

chemical vapor deposition; cluster compounds; heterogeneous catalysis; oxidation; zeolites;

D O I：

10.1002/anie.200502940

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Remarkable selectivity (88% in the steady-state reaction and 94% in the pulse reaction) is observed in the direct synthesis of phenol from benzene with molecular oxygen over a Re/zeolite catalyst prepared by chemical-vapor deposition. The novel interstitial-N/Re clusters are formed with NH3 and are essential for the activity in the selective oxidation reaction. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：448 / 452

页数：5

共 31 条

[1]

[Anonymous], 2005, ANGEW CHEM

[2]

Argauer R.J., 1972, US Pat., Patent No. [3702886, US3702886A]

[3] Coupling of chemical, electrochemical and ultrasonic energies for controlled generation of hydroxyl radicals - Direct synthesis of phenol by benzene hydroxylation [J].