Crystal engineering: The effects of pi-pi interactions in copper(I) and silver(I) complexes of 2,7-diazapyrene

被引：145
作者：
Blake, AJ
Champness, NR
Khlobystov, AN
Lemenovskii, DA
Li, WS
Schroder, M
机构：
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
[2] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 15期
关键词：
D O I：
10.1039/a702050c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ligand 2,7-diazapyrene (L) is used to construct three- and two-dimensional arrays with Cu-I and Ag-I ions: {[(CuL2)-L-I]PF6}(infinity) shows an adamantoid network with three interpenetrating networks, while {[(AgL2)-L-I(MeCN)(2)]BF4}(infinity) forms linear chains of [AgL](infinity) units linked by apparent pi-pi stacking and Ag ... Ag interactions between adjacent diazapyrene ligands to form two-dimensional sheets.
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页码：1339 / 1340
页数：2
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