Adsorption of isomeric aryl- and diadamantane molecules on the surface of graphitized thermal carbon black

被引：3

作者：

Yashkin, S. N. ^{[1
]}

Svetlov, D. A. ^{[1
]}

Sarkisova, V. S. ^{[1
]}

机构：

[1] Samara State Tech Univ, Samara 443100, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 09期

关键词：

aryladamantanes; diadamantanes; graphitized thermal carbon black; Henry's constant; heat of adsorption; entropy of adsorption; model of dimeric ideal gas; THERMODYNAMIC CHARACTERISTICS; HYDROCARBONS; CHROMATOGRAPHY; ADAMANTANE; RETENTION;

D O I：

10.1007/s11172-011-0274-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The thermodynamic characteristics of adsorption of isomeric molecules of 1,1'-, 1,2'-, and 2,2'-diadamantanes, 1- and 2-phenyladamantanes, and 1-cyclohexyladamantane on the surface of graphitized thermal carbon black (GTC) were experimentally determined. The influence of the molecular structure of adsorbates on their adsorption on the basis face of graphite was considered. A high selectivity of the GTC surface for the gas chromatographic separation of mixtures of the considered structural isomers was shown.

引用

页码：1814 / 1819

页数：6

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