The preparation and properties of CeO2-TiO2 film by sol-gel spin-coating process

被引:25
作者
Sakamoto, Hiromichi [1 ]
Qiu, Jianbei [1 ]
Makishima, Akio [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, 1-1 Asahidai, Nomi, Ishikawa 9231292, Japan
关键词
Sol-gel; Thin films; Spin-coating; Optical property; Microstructure;
D O I
10.1016/S1468-6996(03)00011-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ultraviolet absorbing CeO2-TiO2 coatings were prepared by the sol-gel spin-coating process heat treated at 500 degrees C. The films obtained were brilliant yellow, adherent and had some pattern on the soda-lime glass substrate. The optical transmittance, thickness and hardness of the films as a function of the number of coatings, aging time (0, 24, 48, 96 h) or aging temperature (28, 35, 40, 50 degrees C) were determined, and surface microstructure of the films was observed by SEM. We found some pattern on the surface of films. This pattern was similar to that of the stage for fixing the substrate. The pattern on the surface of films would be caused by the difference of thermal conductivity to slide glass in the part of metal of the stage and hollow part of the stage. (C) 2003 Published by Elsevier Science Ltd.
引用
收藏
页码:69 / 76
页数:8
相关论文
共 14 条
  • [1] REVIEW OF SOL-GEL THIN-FILM FORMATION
    BRINKER, CJ
    HURD, AJ
    SCHUNK, PR
    FRYE, GC
    ASHLEY, CS
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 147 : 424 - 436
  • [2] BRITTEN JA, 1992, MATER RES SOC SYMP P, V271, P413, DOI 10.1557/PROC-271-413
  • [3] DU XM, 1995, J AM CERAM SOC, V78, P2254, DOI 10.1111/j.1151-2916.1995.tb08650.x
  • [4] Floch C. J., 1990, SOL GEL SCI, P795
  • [5] Study of time effect on the optical properties of spin-coated CeO2-TiO2 thin films
    Ghodsi, FE
    Tepehan, FZ
    Tepehan, GG
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 68 (3-4) : 355 - 364
  • [6] Optical and electrochromic properties of sol-gel made CeO2TiO2 thin films
    Ghodsi, FE
    Tepehan, FZ
    Tepehan, GG
    [J]. ELECTROCHIMICA ACTA, 1999, 44 (18) : 3127 - 3136
  • [7] Nanoscale radiative striations of sol-gel-derived spin-coating films
    Kozuka, H
    Takenaka, S
    Kimura, S
    [J]. SCRIPTA MATERIALIA, 2001, 44 (8-9) : 1807 - 1811
  • [8] MAKISHIMA A, 1986, J AM CERAM SOC, V69, pC127
  • [9] PREPARATION OF CEO2-TIO2 COATINGS BY THE SOL-GEL PROCESS
    MAKISHIMA, A
    ASAMI, M
    WADA, K
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1988, 100 (1-3) : 321 - 324
  • [10] Ultraviolet ray absorbing coatings on glass for automobiles
    Morimoto, T
    Tomonaga, H
    Mitani, A
    [J]. THIN SOLID FILMS, 1999, 351 (1-2) : 61 - 65