Stereospecific and Reversible CO Binding at Iron Pincer Complexes

被引：91

作者：

Benito-Garagorri, David ^{[1
]}

Puchberger, Michael ^{[2
]}

Mereiter, Kurt ^{[3
]}

Kirchner, Karl ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria

[2] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria

[3] Vienna Univ Technol, Inst Chem Technol & Analyt, A-1060 Vienna, Austria

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 47期

关键词：

carbon monoxide; coordination chemistry; gas sensors; iron; pincer ligands;

D O I：

10.1002/anie.200803665

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) An opening for CO: An iron PNP pincer complex self-assembles in the solid state through intermolecular Fe-Cl⋯H-N hydrogen bonds to form a 3D supramolecular network. This compound reacts readily with gaseous CO in the solid state andin solution to stereospecifically give the octahedral complexes cis- and trans-[Fe(PNP-iPr)(CO)(Cl)2], respectively. In the solid-state process the supramolecular connectivities between individual molecules are maintained without loss of crystallinity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9142 / 9145

页数：4

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