Fabrication of ZnO/Carbon Quantum Dots Composite Sensor for Detecting NO Gas

被引:52
作者
Yu, Ziyang [1 ]
Zhang, Liang [1 ]
Wang, Xiangyue [2 ]
He, Dong [1 ]
Suo, Hui [1 ]
Zhao, Chun [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130118, Peoples R China
[2] Jilin Univ, Coll Chem, Changchun 130118, Peoples R China
关键词
carbon quantum dots; ZnO; gas sensors; NO; NITRIC-OXIDE; TIN OXIDE; NANOPARTICLES; DISEASE;
D O I
10.3390/s20174961
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
ZnO and carbon quantum dots (CQDs) were synthesized by a hydrothermal method, and CQDs were doped into ZnO by a grinding method to fabricate a ZnO/CQDs composite. The X-ray diffraction and the scanning electron microscope revealed that the as-prepared ZnO has a structure of wurtzite hexagonal ZnO and a morphology of a flower-like microsphere which can provide more surface areas to adsorbed gases. The ZnO/CQDs composite has a higher gas sensitivity response to NO gas than ZnO microspheres. A gas sensitivity test of the ZnO/CQDs composite showed that the sensor had a high NO response (238 for 100 ppm NO) and NO selectivity. The detection limit of the ZnO/CQDs composite to NO was 100 ppb and the response and recovery times were 34 and 36 s, respectively. The active functional group provided by CQDs has a significant effect on NO gas sensitivity, and the gas sensitivity mechanism of the ZnO/CQDs composite is discussed.
引用
收藏
页码:1 / 11
页数:11
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