A photoactive basket-like metal-organic tetragon worked as an enzymatic molecular flask for light driven H2 production

被引：51

作者：

He, Cheng ^{[1
]}

Wang, Jian ^{[1
]}

Zhao, Liang ^{[1
]}

Liu, Tao ^{[1
]}

Zhang, Jing ^{[1
]}

Duan, Chunying ^{[1
]}

机构：

[1] Dalian Univ Technol Dalian, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 06期

关键词：

BOND-VALENCE PARAMETERS; ELECTRON-TRANSFER; CRYSTAL-STRUCTURE; HYDROGENASE; COMPLEXES; CHEMISTRY;

D O I：

10.1039/c2cc37853a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A photoactive basket-like metal-organic tetragon Ce-ZL that contained a carbazole photosensitizer was developed to capture the biomimetic [FeFe]-H(2)ases for light driven H-2 production. The system exhibited enzymatic behaviour and its activity was inhibited by the encapsulation of ATP.

引用

页码：627 / 629

页数：3

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