Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes

被引：4

作者：

Bashirov, D. A. ^{[1
,2
]}

Kolybalov, D. S. ^{[1
,2
]}

Sukhikh, T. S. ^{[1
,2
]}

Konchenko, S. N. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

coordinate compounds; lanthanides; thulium; amidinates; formamidinates; synthesis; crystal structure; REACTIVITY; CHEMISTRY; CLUSTERS;

D O I：

10.1134/S0022476620040071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By the interaction of TmCl(3)with KFormDipp (FormDipp = N,N '-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)(2)Cl(THF)](1)and [KTm(FormDipp)(2)Cl-2](2)(2)complexes are obtained. The reaction of1with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)(2)(SPh)(THF)] complex(3).The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases:1a(P-1) and1b(P2(1)/n) phases being two solvent-free polymorphs for complex1;2 center dot 0.5C(7)H(8)> and3 center dot C(7)H(8)phases containing solvate toluene molecules for complexes2and3.

引用

页码：550 / 558

页数：9

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