Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes

被引：4
作者：
Bashirov, D. A. [1 ,2 ]
Kolybalov, D. S. [1 ,2 ]
Sukhikh, T. S. [1 ,2 ]
Konchenko, S. N. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 61卷 / 04期
基金：
俄罗斯科学基金会;
关键词：
coordinate compounds; lanthanides; thulium; amidinates; formamidinates; synthesis; crystal structure; REACTIVITY; CHEMISTRY; CLUSTERS;
D O I：
10.1134/S0022476620040071
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By the interaction of TmCl(3)with KFormDipp (FormDipp = N,N '-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp)(2)Cl(THF)](1)and [KTm(FormDipp)(2)Cl-2](2)(2)complexes are obtained. The reaction of1with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp)(2)(SPh)(THF)] complex(3).The structure of all prepared compounds is determined by single crystal X-ray diffraction of the following solid phases:1a(P-1) and1b(P2(1)/n) phases being two solvent-free polymorphs for complex1;2 center dot 0.5C(7)H(8)> and3 center dot C(7)H(8)phases containing solvate toluene molecules for complexes2and3.
引用
收藏
页码：550 / 558
页数：9
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