Local behaviour of negative thermal expansion materials

被引:24
作者
Fornasini, P [1 ]
Dalba, G
Grisenti, R
Purans, J
Vaccari, M
Rocca, F
Sanson, A
机构
[1] Univ Trent, Dipartimento Fis, Ist Nazl Fis Mat, I-38050 Pavo, Trento, Italy
[2] CNR, Sez CeFSa Trento, IFN, Ist Foton & Nanotecnol, I-38050 Pavo, Trento, Italy
关键词
thermal expansion; framework structures; EXAFS; lattice dynamics;
D O I
10.1016/j.nimb.2005.12.062
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
EXAFS can represent a powerful probe of the local behaviour of negative thermal expansion (NTE) materials, thanks to the possibility of measuring the expansion of selected inter-atomic bonds and the perpendicular relative atomic displacements. The effectiveness of EXAFS for NTE studies is illustrated by a comparison of results recently obtained on germanium, CuCl and the cuprites Cu2O and Ag2O. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:180 / 183
页数:4
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