Iron-Catalyzed Reduction of Carboxylic Esters to Alcohols

被引：59

作者：

Junge, Kathrin ^{[1
]}

Wendt, Bianca ^{[1
]}

Zhou, Shaolin ^{[2
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 2013卷 / 11期

关键词：

Synthetic methods; Homogeneous catalysis; Iron; Reduction; Hydrosilanes; Esters; Alcohols; EFFICIENT HYDROSILYLATION; ASYMMETRIC HYDROSILYLATION; CHEMOSELECTIVE REDUCTION; HYDROSILANE REDUCTION; SELECTIVE REDUCTION; CARBONYL-COMPOUNDS; HYDROGENATION; RUTHENIUM; AMIDES; KETONES;

D O I：

10.1002/ejoc.201300039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel catalytic system formed from Fe(stearate)2/NH2CH2CH2NH2 and polymethylhydrosiloxane was directly developed for the hydrosilylation of carboxylic acid esters to alcohols. The catalytic method exhibits broad substrate scope, including 20 aliphatic, aromatic, and heterocyclic esters. The corresponding alcohols are obtained in moderate to very good yields.

引用

页码：2061 / 2065

页数：5

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