Spatial distribution of organochlorine pesticides (OCPs) and effect of soil characters: A case study of a pesticide producing factory

The distribution and concentration Of some organochlorine pesticides (OCPs) in the soil around a pesticide factory in Zibo, China, were examined, including dichlorodiphenyltrichloroethane (DDT) and its metabolites, isomers of hexachlorocyclohexane (HCH) and endosulfan (ENDO). The results showed that the OCPs concentrations were extraordinary high in this region. The concentrations of DDTs, HCHs, and ENDO were measured in the range of 0.775-226.711, 0.248-42.838, and 0.081-1.644 mg kg(-1), respectively. DDT and its isomers were identified to be the dominate contaminants in most of the sampling sites. In the vertical direction, the distribution pattern of the total OCPs was in order of DDTs, HCHs, and ENDO in the 0-20 cm, but in 20-40 and 40-60 cm the trends were unobvious. Although no recent input occurred in most areas, the residues of OCPs remained in deep soil due to their persistence. Unlike ENDO, DDTs and HCHs appeared to have the similar property in terms of not only the migration pattern in soil, but also the relationship to the same dominant impact factor (i.e. organic matter). DDTs and HCHs were affected positively by the organic matter, whereas ENDO was affected negatively. Due to the interrelationship among various impact factors, the spatial distribution of pesticides in the soil was considered to be a combined result. (C) 2012 Elsevier Ltd. All rights reserved.