Solvothermal synthesis and luminescent properties of Y2Ti2O7:Eu3+ spheres

被引:21
作者
Pavitra, E. [1 ]
Raju, G. Seeta Rama [1 ]
Yu, Jae Su [1 ]
机构
[1] Kyung Hee Univ, Dept Elect & Radio Engn, Yongin 446701, South Korea
来源
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS | 2013年 / 7卷 / 03期
关键词
Y2Ti2O7:Eu3+ phosphors; spherical morphology; solvothermal method; luminescence; PYROCHLORE; PHOSPHORS; EU3+;
D O I
10.1002/pssr.201206484
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Pyrochlore-structured yttrium titanate phosphors activated by trivalent europium ions (Y2Ti2O7(YT):Eu3+), with spherical morphology, were synthesized at different pH values by a solvothermal process. From the structural and morphological measurements, the annealing temperature had no effect on the spherical morphology of the YT:Eu3+ sample. The photoluminescence excitation and emission spectra were taken by activating the Eu3+ ions in the YT host lattice as functions of Eu3+ ion concentration and annealing temperature. The optimal doping concentration was found to be 4 mol%, exhibiting an excellent orange-red emission due to the highest intensity of the D-5(0) -> F-7(1) transition. When the YT:Eu3+ phosphor was mixed with YAG:Ce3+ phosphor, a brilliant white light emission was achieved. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:224 / 227
页数:4
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