Oxygen/phosphorus co-doped porous carbon from cicada slough as high-performance electrode material for supercapacitors

被引:58
作者
Chen, Bingwei [1 ,2 ,3 ,4 ]
Wu, Wenzhuo [5 ]
Li, Chunyang [1 ,2 ]
Wang, Yanfang [1 ,2 ,3 ,4 ]
Zhang, Yi [1 ,2 ]
Fu, Lijun [1 ,2 ]
Zhu, Yusong [1 ,2 ]
Zhang, Lixin [3 ,4 ]
Wu, Yuping [1 ,2 ,3 ,4 ]
机构
[1] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, Sch Energy Sci & Engn, Nanjing 211816, Jiangsu, Peoples R China
[3] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China
[4] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[5] Guanghua Cambridge Int Sch, Shanghai 201315, Peoples R China
关键词
ACTIVATED CARBON; RICE HUSK; PHOSPHORUS; NITROGEN; BIOMASS; CAPACITANCE; COMPOSITES; GRAPHENE; FIBERS; SHELLS;
D O I
10.1038/s41598-019-41769-y
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Synthesizing high-performance electrode materials plays a vital role in fabricating advanced supercapacitors. Heteroatom doping has been proved to be effective in enhancing the electrochemical properties of carbon-based electrodes. Herein, we report an O, P co-doped porous carbon (PC) originated from waste biomaterials, cicada sloughs. The PC possesses meso-/microporous structure with a large specific surface area (1945 m(2).g(-1)) and a high O, P co-doping ratio of 18 wt%. These superior factors together enable it to deliver high specific capacitance (295 F.g(-1) in 6 M KOH and 291 F.g(-1) in 1 M H2SO4), good cycling stability (100% capacitance retention after 10000 cycles in 1 M H2SO4) and rate performance. Therefore, from the respects of environment friendliness and cost effectivity, obtaining heteroatom doped carbons from the nature might be better compared to pyrolyzing heteroatom-containing chemicals.
引用
收藏
页数:8
相关论文
共 48 条
[1]   Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review [J].
Abioye, Adekunle Moshood ;
Ani, Farid Nasir .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 52 :1282-1293
[2]   High voltage supercapacitor built with seaweed carbons in neutral aqueous electrolyte [J].
Bichat, M. P. ;
Raymundo-Pinero, E. ;
Beguin, F. .
CARBON, 2010, 48 (15) :4351-4361
[3]   Hierarchically porous carbon by activation of shiitake mushroom for capacitive energy storage [J].
Cheng, Ping ;
Gao, Shuangyan ;
Zang, Peiyu ;
Yang, Xiaofan ;
Bai, Yonglong ;
Xu, Hua ;
Liu, Zonghuai ;
Lei, Zhibin .
CARBON, 2015, 93 :315-324
[4]   Micro-mesoporous carbon spheres derived from carrageenan as electrode material for supercapacitors [J].
Fan, Yang ;
Yang, Xin ;
Zhu, Bing ;
Liu, Pei-Fang ;
Lu, Hai-Ting .
JOURNAL OF POWER SOURCES, 2014, 268 :584-590
[5]   Preparation of highly porous binderless activated carbon electrodes from fibres of oil palm empty fruit bunches for application in supercapacitors [J].
Farma, R. ;
Deraman, M. ;
Awitdrus, A. ;
Talib, I. A. ;
Taer, E. ;
Basri, N. H. ;
Manjunatha, J. G. ;
Ishak, M. M. ;
Dollah, B. N. M. ;
Hashmi, S. A. .
BIORESOURCE TECHNOLOGY, 2013, 132 :254-261
[6]   Carbon materials for supercapacitor application [J].
Frackowiak, Elzbieta .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (15) :1774-1785
[7]   Microporous carbon from a biological waste-stiff silkworm for capacitive energy storage [J].
Gong, Chengcheng ;
Wang, Xinzhu ;
Ma, Danhua ;
Chen, Huifeng ;
Zhang, Shanshan ;
Liao, Zhixin .
ELECTROCHIMICA ACTA, 2016, 220 :331-339
[8]   Electrochemically Active Phosphotungstic Acid Assisted Prevention of Graphene Restacking for High-Capacitance Supercapacitors [J].
He, Chengen ;
Qiu, Shengqiang ;
Sun, Shan ;
Zhang, Qing ;
Lin, Guanyu ;
Lei, Sheng ;
Han, Xiaoyan ;
Yang, Yingkui .
ENERGY & ENVIRONMENTAL MATERIALS, 2018, 1 (02) :88-95
[9]   Rice husk-derived porous carbons with high capacitance by ZnCl2 activation for supercapacitors [J].
He, Xiaojun ;
Ling, Pinghua ;
Yu, Moxin ;
Wang, Xiaoting ;
Zhang, Xiaoyong ;
Zheng, Mingdong .
ELECTROCHIMICA ACTA, 2013, 105 :635-641
[10]   Cicada slough-derived heteroatom incorporated porous carbon for supercapacitor: Ultra-high gravimetric capacitance [J].
Jia, Haiyang ;
Sun, Jiawei ;
Xie, Xiao ;
Yin, Kuibo ;
Sun, Litao .
CARBON, 2019, 143 :309-317