Solid-state solar modules based on mesoscopic organometal halide perovskite: a route towards the up-scaling process

被引：162
作者：
Matteocci, F. [1 ]
Razza, S.
Di Giacomo, F. [1 ]
Casaluci, S. [1 ]
Mincuzzi, G. [1 ]
Brown, T. M. [1 ]
D'Epifanio, A. [2 ]
Licoccia, S. [2 ]
Di Carlo, A. [1 ]
机构：
[1] Univ Roma Tor Vergata, CHOSE, Dept Elect Engn, I-00133 Rome, Italy
[2] Univ Roma Tor Vergata, Dept Chem Sci & Technol, I-00133 Rome, Italy
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 09期
关键词：
CELLS; EFFICIENCY; MECHANISM; TIO2; DEVICE;
D O I：
10.1039/c3cp55313b
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We fabricated the first solid state modules based on organometal halide perovskite CH3NH3PbI3-xClx using Spiro-OMeTAD and poly-(3-hexylthiophene) as hole transport materials. Device up-scaling was performed using innovative procedures to realize large-area cells and the integrated series-interconnections. The perovskite-based modules show a maximum conversion efficiency of 5.1% using both poly(3-hexylthiophene) and Spiro-OMeTAD. A long-term stability test was performed (in air, under AM1.5G, 1 Sun illumination conditions) using both materials showing different behaviour under continuous light stress. Whilst the poly(3-hexylthiophene)-based module efficiency drops by about 80% with respect to the initial value after 170 hours, the Spiro-based module shows a promising long-term stability maintaining more than 60% of its initial efficiency after 335 hours.
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收藏
页码：3918 / 3923
页数：6
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