Mukaiyama Aldol Reactions in Aqueous Media

被引：80

作者：

Kitanosono, Taku ^{[1
]}

Kobayashi, Shu ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Hongo, Tokyo, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 16期

基金：

日本学术振兴会;

关键词：

aldol reaction; asymmetric catalysis; green chemistry; Lewis acids; water; SILYL ENOL ETHERS; LEWIS-ACID CATALYSTS; DIELS-ALDER REACTIONS; SURFACTANT-COMBINED CATALYSTS; SUPPORTED SCANDIUM CATALYST; HOST-GUEST COMPLEXATION; CARBON BOND FORMATION; EFFECTIVE IONIC-RADII; ORGANIC-REACTIONS; COPPER(II) COMPLEXES;

D O I：

10.1002/adsc.201300798

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mukaiyama aldol reactions in aqueous media have been surveyed. While the original Mukaiyama aldol reactions entailed stoichiometric use of Lewis acids in organic solvents under strictly anhydrous conditions, Mukaiyama aldol reactions in aqueous media are not only suitable for green sustainable chemistry but are found to produce singular phenomena. These findings led to the discovery of a series of water-compatible Lewis acids such as lanthanide triflates in 1991. Our understanding on these beneficial effects in the presence of water will be deepened through the brilliant examples collected in this review.

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页码：3095 / 3118

页数：24

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