Chiral selectors in CE: Recent developments and applications

被引：91

作者：

Tsioupi, Despina A. ^{[1
]}

Stefan-van Staden, Raluca-Ioana ^{[2
,3
]}

Kapnissi-Christodoulou, Constantina P. ^{[1
]}

机构：

[1] Univ Cyprus, Dept Chem, Nicosia, Cyprus

[2] Natl Inst Res Electrochem & Condensed Matter, Lab Electrochem, Bucharest, Romania

[3] Natl Inst Res Electrochem & Condensed Matter, PATLAB Bucharest, Bucharest, Romania

来源：

ELECTROPHORESIS | 2013年 / 34卷 / 01期

关键词：

CE; Chiral selectors; Chiral separations; OPEN-TUBULAR CAPILLARY; PERFORMANCE LIQUID-CHROMATOGRAPHY; CATIONIC BETA-CYCLODEXTRIN; HOST-GUEST COMPLEXATION; SUPERCRITICAL-FLUID CHROMATOGRAPHY; MONOLITHIC STATIONARY PHASES; NUCLEAR-MAGNETIC-RESONANCE; DIODE-ARRAY DETECTION; ALPHA-AMINO-ACIDS; ENANTIOMERIC SEPARATION;

D O I：

10.1002/elps.201200239

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

This review article provides an overview of the recent advances in enantioanalysis by use of electrophoretic techniques. Due to the big number of publications in the subject mentioned above, this article is focused on chiral method developments and applications published from 2008 until 2011, and it demonstrates chiral selectors used in CE. Numerous chiral selectors have been used over the years, and these include the cyclic and the linear oligo- and polysaccharides, the branched polysaccharides, the polymeric and monomeric surfactants, the macrocyclic and other antibiotics, and the crown ethers. Different dual-selector systems are also presented in this article, and the results are compared with those obtained by use of a single chiral selector. Finally, several pharmaceutical and biomedical applications based on chiral recognition are summarized.

引用

页码：178 / 204

页数：27

共 247 条

[1] Enantiomeric separation of aminoglutethimide by capillary electrophoresis using native cyclodextrins in single and dual systems [J].