Crystal Structure of Binuclear Cobalt Complexes [(Cp′"Co)2(μ2-η1:η2-S2)2] and [(Cp′"Co)2(μ2-η1:η2-Se2)2]

被引：3

作者：

Afonin, M. Yu. ^{[1
]}

Sukhikh, T. S. ^{[1
,2
]}

Konchenko, S. N. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

synthesis; binuclear complexes; cobalt; sulfur; selenium; crystal structure; TRIPLE-DECKER; ARENE; REACTIVITY; LIGANDS; RICH;

D O I：

10.1134/S0022476618010201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binuclear cobalt complexes [(Cp'''Co)(2)(mu(2)-eta(1):eta(2)-S-2)(2)] (1) (Cp''' = eta(5)-1,2,4-tris(tert-butyl)cyclopentadienide) and [(Cp'''Co)(2)(mu(2)-eta(1):eta(2)-Se-2)(2)] (2) are obtained by the interaction of [(Cp'''Co)(2)(mu-eta(4):eta(4)-C7H8)] with excess sulfur or selenium respectively. The structures of the complexes are determined by single crystal X-ray diffraction.

引用

页码：136 / 139

页数：4

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